Brown butter flavor ยท compound library & formulation

Brown butter flavor ยท compound library & formulation
Photo by Wagner Vilas / Unsplash

The flavor compounds listed here are suggested by Judith Michalski, a well known flavorist in the book "Successful Flavors" for making a brown butter flavor. For each compound, additional information is provided here including flavor descriptors and suggested usage levels for making this flavor. The flavor notes for a brown butter flavor includes five major and 17 minor notes.

Brown butter ยท compound library & formulation

๐Ÿงˆ Brown butter flavor ยท compound set

alphabetical index with FEMA, sensory, and typical levels (ppm in finished product)
CompoundFEMAFlavor descriptors (brown butter context)Suggested usage (ppm)
1-octen-3-ol2805Mushroom, earthy, fungal, raw, oily, cooked vegetable0.2โ€“1
2,3-hexanedione2558Buttery, sweet, caramel, toasted, creamy, slightly sharp1โ€“4
2,3-pentanedione2841Strong buttery, creamy, sweet, nutty, toasted, caramelic1โ€“5
2,4-decadienal3135Deep fried, fatty, chicken fat, waxy, oily, oxidized citrus0.02โ€“0.2 (ppb range)
2-acetyl furan3163Sweet, nutty, bready, roasted, coffee, slightly smoky1โ€“5
2-acetyl pyrazine3126Popcorn, nutty, roasted, toasted bread, corn chip0.5โ€“3
2-acetyl thiazole3328Popcorn, nutty, roasted, cereal, meaty, sulfury0.3โ€“2
2-acetyl-3,5(&6)dimethylpyrazine3329 / 4100Nutty, roasted, earthy, cocoa, baked potato, coffee0.2โ€“2
2-heptanone2544Cheesy, fruity, ketonic, waxy, blue cheese nuance1โ€“8
2-nonanol3315Waxy, clean, fatty, green melon, creamy, faint citrus0.3โ€“2.5
2-tridecanone3388Waxy, dairy, coconut, fatty, cheesy, earthy, hay1โ€“6
2-undecanone3093Waxy, fruity, creamy, fatty, green rindy, floral0.5โ€“4
3,4-xylenolโ€” (alt. 3495)Phenolic, medicinal, smoky, woody, tarry0.01โ€“0.1
3-methyl pentanoic acid3437Sweaty, cheesy, sour, fermented, animal, fruity nuance1โ€“6
4-ethyl phenol3156Phenolic, smoky, medicinal, leather, barnyard, spicy0.05โ€“0.5
5,6-decenoic acid3742Waxy, creamy, peach-like, dairy, milky, soapy1โ€“5
5,6,7,8-tetrahydroquinoxalineโ€” (similar 3321)Nutty, roasted, popcorn, earthy, pyrazine-like0.2โ€“1.5
acetoin2008Creamy, buttery, fatty, milky, yogurt, slight sour15โ€“50
butyl undeconeate (undecylenate)โ€” (undecylenate 4622)Waxy, fatty, fruity, slightly metallic0.5โ€“3
butyric acid2221Rancid, cheesy, butter, creamy at low dose, fermented8โ€“25
cis-4-heptenal3289Creamy, milky, fatty, oily, vegetative, fresh dairy0.005โ€“0.1 (ppbโ€“low ppb)
cyclotene (methyl cyclopentenolone)2700Caramel, maple, sweet, burnt sugar, brown, seasoning5โ€“20
decanoic acid2364Fatty, soapy, waxy, cheesy, goat-like, rancid2โ€“12
diacetyl2370Intense buttery, creamy, artificial butter, pungent3โ€“8
dimethyl sulfide2746Sweet corn, creamy, milky, sulfurous, tomato, fresh0.1โ€“0.5
ฮด-decalactone2361Creamy, coconut, peach, fatty, rich milky5โ€“20
ฮด-dodecalactone2401Strong creamy, coconut, buttery, waxy, dairy5โ€“18
ฮด-nonalactone3356Coconut, creamy, milky, waxy, coumarinic3โ€“15
ฮด-tetradecalactone3590Fatty, waxy, creamy, rich mouthfeel, peach skin3โ€“15
furanol (furaneol)3174Sweet, caramel, cotton candy, burnt sugar, fruity, strawberry5โ€“25
furfural2489Sweet, almond, baked bread, burnt, caramelic, nutty2โ€“12
heptanoic acid3348Rancid, fatty, cheesy, sweaty, waxy, sour1โ€“7
hexanoic acid2559Sweaty, cheesy, fatty, goat, pungent, waxy2โ€“12
indole2593Animal, fecal (trace), floral in dilution, complexing0.01โ€“0.05 (trace)
isopentanoic acid (3-methylbutanoic)3102Sweaty, cheesy, rancid, fermented, dirty dairy1โ€“8
lauric acid2614Waxy, fatty, mild soapy, creamy, bay oil2โ€“12
maltol2656Sweet, caramel, cotton candy, fruity, creamy enhancer8โ€“35
methyldihydrocyclopentapyrazineโ€” (related 3309)Nutty, roasted, coffee, cocoa, earthy, popcorn0.2โ€“2
myristic acid2764Waxy, faintly oily, soapy, fatty background2โ€“12
nonanal2782Waxy, fatty, citrus, green, fresh, oily, floral0.2โ€“2
nonanoic acid2784Fatty, waxy, cheesy, nutty, green animal1โ€“8
octanoic acid2799Fatty, waxy, rancid, cheesy, sweaty, fruity1โ€“10
oleic acid2815Fatty, oily, lard-like, smooth2โ€“15
p-cresol2337Phenolic, medicinal, animal, woody, tar-like0.02โ€“0.1
palmitic acid2832Nearly odorless, waxy, adds body and fatty perception2โ€“15
skatole3019Fecal, animal, floral at extreme dilution, complexing0.005โ€“0.02 (ppb)
stearic acid3035Odorless, waxy, adds fatty mouthfeel2โ€“15
sulfurol (2-furanmethanethiol)3163 (furanthiol)Roasted coffee, meaty, sulfurous, burnt, popcorn0.01โ€“0.1
vanillin3107Sweet, creamy, vanilla, heliotrope, smooth8โ€“40
ฮณ-butyrolactone3291Creamy, fatty, caramelic, slightly fruity, coconut5โ€“20

๐Ÿ”ฅ Formulation: brown butter โ€“ 5 dominant + 17 minor notes

brown buttery caramel creamy nutty ยท plus animal, butterscotch, cooked milk, corny, cowy, fatty, milky, oxidized, phenolic, popcorn, rancid, soapy, sweaty, sweet, toffee, waxy.

๐Ÿฅจ brown ยท caramel ยท toffee ยท butterscotch

Furaneol 10โ€“20 ppm, cyclotene 6โ€“15 ppm, maltol 15โ€“25 ppm, 2,3-hexanedione 2โ€“4 ppm, 2,3-pentanedione 2โ€“5 ppm, furfural 3โ€“10 ppm. These build the core brown/caramelized/toffee character. Vanillin 10โ€“25 ppm adds sweet smoothness.

๐Ÿงˆ buttery ยท creamy ยท milky ยท cooked milk

Diacetyl 3โ€“6 ppm, acetoin 20โ€“40 ppm, butyric acid 12โ€“20 ppm, ฮด-lactones (C10, C12, C14) 5โ€“18 ppm each, ฮณ-butyrolactone 5โ€“15 ppm, cis-4-heptenal 0.01โ€“0.05 ppm for creamy/fresh milk lift. DMS 0.15โ€“0.4 ppm for cooked milk/corny.

๐Ÿฅœ nutty ยท popcorn ยท roasted

2-acetyl pyrazine 1โ€“3 ppm, 2-acetyl thiazole 0.5โ€“2 ppm, 2-acetyl-3,5-dimethylpyrazine 0.5โ€“2 ppm, 5,6,7,8-tetrahydroquinoxaline 0.5โ€“1.5 ppm, methyldihydrocyclopentapyrazine 0.3โ€“1.5 ppm, sulfurol 0.02โ€“0.08 ppm (roasted/nutty/popcorn).

๐Ÿ„ animal ยท cowy ยท phenolic ยท sweaty ยท rancid

Skatole 0.005โ€“0.02, indole 0.01โ€“0.04, p-cresol 0.02โ€“0.08, 4-ethyl phenol 0.05โ€“0.2, 3,4-xylenol 0.02โ€“0.08. Fatty acids: isopentanoic, 3-methyl pentanoic, hexanoic, octanoic, heptanoic, decanoic 2โ€“10 ppm each โ€“ provide sweaty/rancid/cowy depth.

๐Ÿ•ฏ๏ธ fatty ยท waxy ยท soapy ยท corny ยท oxidized

Oleic, myristic, palmitic, stearic, lauric, nonanoic acids 2โ€“12 ppm. 2,4-decadienal 0.02โ€“0.1 (oxidized), nonanal 0.2โ€“1 (waxy), 2-nonanol 0.5โ€“2, 2-undecanone 0.5โ€“3, 2-tridecanone 1โ€“4. DMS 0.2โ€“0.5 gives corny. Butyl undeconeate adds waxy ester lift.

๐Ÿฟ popcorn ยท butterscotch ยท sweet ยท milky

Already covered by pyrazines, thiazole, furaneol, maltol, vanillin. Ensure 2-acetyl pyrazine + 2-acetyl thiazole at 1โ€“3 ppm for popcorn. Butterscotch = cyclotene + diacetyl + vanillin. Sweet = vanillin/maltol. Milky = lactones + cis-4-heptenal.

๐Ÿ“‹ FEMA numbers verified where possible; some compounds (methyldihydrocyclopentapyrazine) have similar identifiers. Butyl undeconeate = undecylenate. Use levels as starting points โ€“ iterative sensory tuning essential.

Formulation Strategy for Brown Butter

The document provides a structured approach to building the complex brown butter profile. The five dominant notes are constructed using specific chemical families, while the 17 minor notes emerge from the careful balance of these same ingredients.

  • Brown, Caramel, Toffee Backbone: Built with furaneol, cyclotene, maltol, furfural, and the diones (2,3-hexanedione, 2,3-pentanedione). Vanillin adds smooth sweetness.
  • Buttery and Creamy Heart: Driven by diacetyl, acetoin, butyric acid, and a blend of ฮด-lactones (C10, C12, C14) and ฮณ-butyrolactone.
  • Nutty and Popcorn Layer: Created by acetyl pyrazines, acetyl thiazole, and other alkylpyrazines, with sulfurol adding a roasted note.
  • Fatty, Waxy Foundation: A blend of fatty acids (C8โ€“C18) and methyl ketones (2-nonanol, 2-undecanone, 2-tridecanone) provides body.
  • Complexing Trace Notes: Minute amounts of skatole, indole, p-cresol, and alkyl phenols add animalic, phenolic, and "cowy" depth.
  • Oxidized and Cooked Accents: Provided by dimethyl sulfide (DMS), 2,4-decadienal, and cis-4-heptenal at very low levels.

How is browned butter commercially manufactured?

The industrial manufacturing of browned butter is a sophisticated, continuous process designed to produce a consistent product with the characteristic nutty flavor and brown color, avoiding the pitfalls of the stovetop method . This patented technology, developed by companies like Land O'Lakes, transforms regular butter on a large scale through precise, controlled steps .

Here is a step-by-step breakdown of the industrial process:

Step Environment Key Action Purpose & Conditions
1. Preparation Heating Vessel Melt the starting composition (e.g., butter). Liquefy standard butter (approx. 80% fat, 16% water) for processing .
2. Concentration Evaporator Device (under vacuum) Remove water under vacuum. Reduce moisture content to a precise level (<3% variation) without burning solids .
3. Browning Reaction Vessel Apply heat to trigger the Maillard reaction. Controlled heating causes proteins and sugars to react, forming brown color & nutty flavor .
4. Finishing Cooling & Packaging Vessels Cool and prepare the final product. Cool rapidly to stop the reaction, stabilize texture, and package for distribution .

๐Ÿง‘๐Ÿ”ฌ A Unique Structure

This manufacturing method results in a brown butter product with a physical structure different from what you'd get at home. The patented process creates a unique crystal network where:

  • Reacted Solids: The browned milk protein and sugar particles (from the Maillard reaction) act as a core.
  • Fat Crystals: Microscopic ("nascent") fat crystals form around these particles. Larger fat crystals then connect to these, creating a stable web that suspends the flavorful solids throughout the product .

This industrial process stands in contrast to the home cook's method of simply melting butter in a pan and carefully watching for the moment the milk solids brown .

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